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Magnetic structure and phase diagram of the frustrated spinel Cd1−xZnxCr2Se4 |
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| Authors: | E Loudghiri A Belayachi M Nogues M Taibi MM Cruz M Godinho |
| Institution: | 1. Laboratoire de Physique des Matériaux, Faculté des Sciences, Université Mohammed V, B.P. 1014 Rabat, Morocco;2. Laboratoire de Magnétisme et d’Optique de l’Université de Versailles (URA 1531), Batiment, Fermat, 45 Avenue des Etats Unis, 78035 Versailles Cedex, France;3. Laboratoire de Physico-Chimie des Matériaux associé à l’AUF (LAF 502), Ecole Normale, Supérieure Takadoum, B.P. 5118 Rabat, Morocco;4. Dept. Fisica/CFMC-UL, Fac. Ciências, Universidade de Lisboa, Campo Grande, Ed.C8, 1749-016 Lisboa, Portugal |
| Abstract: | In attempt to characterise the magnetic ordering in the whole composition range of the Cd1−xZnxCr2Se4 system, various magnetic measurements were performed on both crystalline and polycrystalline samples with 0?x?1. The magnetic properties of the system are typical of a ferromagnet below x=0.4 and of a complex antiferromagnet one above x=0.6. In this work the intermediate region was carefully studied. The variations of both M(T) and χac at low fields suggest that transitions from ferromagnetic to Gabay–Toulouse ferromagnetic-spin-glass mixed phase at low temperature occur in the range 0.41?x?0.58. The high-temperature susceptibility measurements show that for the whole concentration range the system obeys Curie–Weiss laws. The results can be explained by the coexistence of competing interactions (ferromagnetic between nearest neighbours and antiferromagnetic between higher order neighbours) and disorder due to the random substitution between zinc and cadmium ions in the tetrahedral sites of the spinel lattice. An experimental magnetic phase diagram of the system is established. |
| Keywords: | 75 30 Kz 75 40 Cx 75 40 Gb 75 50 Lk |
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