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THE OBSERVATION OF INTERNAL MOTION OF LINEAR POLYSTYRENE CHAINS IN CYCLOHEXANE AROUND θ TEMPERATURE
基金项目:The work was financially supported by the Chinese Academy of Sciences (CAS) Special Grant,the National Natural Science Foundation of China (NNSFC) Projects,the Hong Kong Special Administration Region (HKSAR) Earmarked Project
摘    要: A high molecular weight (Mw = 1.85 × 107) polystyrene (PS) with narrow distribution was prepared by high vacuum anionic polymerization in tetrahydrofuran. By use of dynamic light scattering, the dynamics of PS chains in cyclohexane was studied around the θ temperature. For the first time, we have observed the internal motion of polymer chains in solutions below the θ temperature by using dynamic light scattering at smaller angles (even qRg < 1).

收稿时间:2007-11-07
修稿时间:2008-01-07
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