Hydrothermal Synthesis and Crystal Structure of Iron Molybdophosphate Fe[Mo_6O_(12)(OH)_3(H_2PO_4)(HPO_4)_2(PO_4)]_2- [Fe(2,2′-bipy)(H_2O)_2]_2[Fe(2,2′-bipy)_3]_2·6H_2O
GUO Hong-Xua,b LIU Shi-Xionga,c② a (Department of Chemistry,Fuzhou University,Fuzhou 350002,China) b (Department of Chemistry,Zhangzhou Teachers College,Zhangzhou 363000,China) c (State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China)
基金项目:
This work was supported by the National Natural Science Foundation of China (20431010, 20171012) and Natural Science Foundation of Fujian Province (E0110010)
摘 要:
1 INTRODUCTION Organic-inorganic hybrid materials and polyoxo-metalates have received much attention because of their intriguing structural diversity and potential applications in molecular adsorption, ion exchange, heterogeneous catalysis and nanotech nology as well as in electrical, magnetic and photochemical areas[1, 2]. One of the important ad- vances in the design of new organic-inorganic hybrid materials is utilizing poly- oxometalates’ coordination ability to produce poly- oxoanio…