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Simultaneous determination of nitrophenol isomers at the single-wall carbon nanotube compound conducting polymer film modified electrode
作者姓名:ZHANG Hui  WANG Zhenhui & ZHOU Shuping College of Chemistry and Environmental Science  Key Laboratory of Environmental Science and Engineering  Education Commission of Henan Province  Henan Normal University  Xinxiang  China
作者单位:ZHANG Hui,WANG Zhenhui & ZHOU Shuping College of Chemistry and Environmental Science,Key Laboratory of Environmental Science and Engineering,Education Commission of Henan Province,Henan Normal University,Xinxiang 453002,China
基金项目:河南省自然科学基金,the Key Laboratory of Environmental Science and Engineering
摘    要:One of the challenging areas of electrochemistry and electroanalytical chemistry is the simultaneous determination of isomers at the same electrode. Con- ventional electrode only possesses a single function of electron transfer; therefore, it is difficult…


Simultaneous determination of nitrophenol isomers at the single-wall carbon nanotube compound conducting polymer film modified electrode
ZHANG Hui,WANG Zhenhui & ZHOU Shuping College of Chemistry and Environmental Science,Key Laboratory of Environmental Science and Engineering,Education Commission of Henan Province,Henan Normal University,Xinxiang ,China.Simultaneous determination of nitrophenol isomers at the single-wall carbon nanotube compound conducting polymer film modified electrode[J].Science in China(Chemistry),2005,48(3).
Authors:ZHANG Hui  Wang Zhenhui  Zhou Shuping
Institution:College of Chemistry and Environmental Science, Key Laboratory of Environmental Science and Engineering, Education Commission of Henan Province, Henan Normal University, Xinxiang 453002, China
Abstract:Based on the molecular recognition ability of conductive polymer and the peculiar properties of carbon nanotubes, a novel single wall nanotubes (SWNTs) compound poly(4- aminopyridine) modified electrode (SWNTs/POAPE) is prepared at glass carbon electrode (GCE). The electrochemistry response of nitrophenol isomers is studied at the SWNTs/POAPE. The re-sult indicates that o-, m- and p-nitrophenol are separated entirely at the SWNTs/POAPE interface. The electrode present here can be easily used to determine nitrophenol isomers simultaneously with higher sensitivity.
Keywords:carbon nanotube compound poly (4-aminopyridine)  modified electrode  nitrophenol  isomer  voltammetry  
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