Intramolecular electron transfer in mixed-valence complexes [(NH3)5Ru-L-Ru(NH3)5]5+ (L = N2, pyz, pym, 4,4′-bipy, bpa) |
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| Authors: | O V Sizova V I Baranovskii A I Panin N V Ivanova |
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| Institution: | (1) St. Petersburg State University, USSR |
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| Abstract: | The dynamics of the intramolecular electron transfer from Ru(II) to Ru(III) in binuclear mixedvalence complexes (NH3)5Ru-L- Ru(NH3)5]5+ (L = N2,pyz, bipy, pym, bpa) is analyzed by the semiempirical CINDO +CI method.
Translated fromZhumal Strukturnoi Khimii, Vol. 39, No. 4, pp. 579–590, July–August, 1998. |
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