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Intramolecular electron transfer in mixed-valence complexes [(NH3)5Ru-L-Ru(NH3)5]5+ (L = N2, pyz, pym, 4,4′-bipy, bpa)
Authors:O V Sizova  V I Baranovskii  A I Panin  N V Ivanova
Institution:(1) St. Petersburg State University, USSR
Abstract:The dynamics of the intramolecular electron transfer from Ru(II) to Ru(III) in binuclear mixedvalence complexes (NH3)5Ru-L- Ru(NH3)5]5+ (L = N2,pyz, bipy, pym, bpa) is analyzed by the semiempirical CINDO +CI method. Translated fromZhumal Strukturnoi Khimii, Vol. 39, No. 4, pp. 579–590, July–August, 1998.
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