On the mechanism of autocatalysis in carbohydrate synthesis from formaldehide |
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| Authors: | T I Khomenko O A Golovina M M Sakharov O V Krylov and A H Weiss |
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| Institution: | (1) Institute of Chemical Physics, Moscow, USSR;(2) Department of Chemical Engineering, Polytechnic Institute, Worcester, Massachusetts, USA |
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| Abstract: | From the analysis of kinetic behaviour in carbohydrate synthesis from formaldehyde and spectral data on the structure of catalytically active Ca(OH)2 complexes with carbohydrates a step-wise mechanism of autocatalysis of formaldehyde condensation to carbohydrates in the presence of Ca(OH)2 is proposed. A kinetic equation to describe the initial step of autocatalysis is given.
                      -      - Ca(OH)2.   ,   .
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