The cis-effect in trans-[PtCl2XY] compounds |
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| Authors: | A F Schreiner T B Brill |
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| Institution: | (1) Department of Chemistry, North Carolina State University, 27607 Raleigh, North Carolina |
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| Abstract: | The cis-influence observed in chlorine NQR data of X, Y affecting the Pt-Cl bonds in compounds of type trans-PtCl2XY] is interpreted.  -bonding differences in Pt-Cl bonds are suggested to account for the trends in NQR frequencies. Pt-Cl  -bonding is negligibly small for both d
(Pt)–p
(Cl) and p
–p
(Cl) interactions. |
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| Keywords: | |
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