Thermodynamics of complex formation reactions between d metals and linear oligopyrroles |
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| Authors: | E. V. Antina G. B. Guseva M. B. Berezin A. I. V’yugin |
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| Affiliation: | (1) Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia |
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| Abstract: | The interaction of alkyl-substituted α,α-dipyrrolylmethenes with d metal acetates and acetylacetonates was studied by spectrophotometric and calorimetric titration methods. The thermodynamics of complex formation reactions between d metal ions and dipyrrolyl ligands was found to depend on the entropy and enthalpy contributions, the nature of a metal, and on the solvation factors. |
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