Biomolecules as promising ligands in the synthesis of metal nanoclusters: Sensing,bioimaging and catalytic applications |
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| Institution: | 1. Key Laboratory of Luminescent and Real-Time Analytical Chemistry, Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China;2. School of Chemistry and Environment, Beihang University, Beijing 100191, China;1. Department of Applied Chemistry, S. V. National Institute of Technology, Surat 395 007, India;2. Chemical Engineering Department, S. V. National Institute of Technology, Surat 395 007, India |
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| Abstract: | The use of metal nanoclusters as sensing probes has recently attracted considerable interest from researchers. In particular, metallic nanoclusters (e.g., Au, Ag, Cu, Pt) have been noticed a wide range of applications in the field of fluorescence sensing and bioimaging. The stabilization of metal nanoclusters with organic molecules, proteins, and amino acids enhances their optical properties and analytical applications. In this review, synthetic routes for the fabrication of metal nanoclusters are summarized. This review also describes the metal nanoclusters properties including aggregation-induced emission, optical absorption, non-linear optical, and chiral properties. We discussed the analytical applications of metal nanoclusters for sensing of wide variety of analytes including drugs, biomolecules, biomarkers. Further, the catalytic applications of metal nanoclusters are also briefly summarized. Finally, we summarize the challenges and future perspectives of metal nanoclusters in analytical chemistry. |
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| Keywords: | Metal nanoclusters Biomolecules Synthetic routes Properties Fluorescence spectrometry Sensing Catalytic applications |
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