The aromatic carbon-carbon ipso-substitution reaction |
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| Authors: | Bonesi Sergio M Fagnoni Maurizio |
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| Affiliation: | CIHIDECAR-CONICET, Departamento de Química Orgánica, 3er Piso, Pabellón 2, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, CP1428, Universidad de Buenos Aires, Argentina. |
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| Abstract: | The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based leaving groups including alkyl, carbinol, CN, COOH, and carbonyl groups in arylation reactions will be illustrated accordingly for the preparation of biphenyl-, vinyl-, alkynyl-, and alkyl-substituted aromatics. |
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| Keywords: | Ar–C bonds aromatic substitution arylation C‐based leaving groups cleavage reactions |
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