Reaction of dimethyl sulfite with dimethylaminomethyl derivatives |
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| Authors: | S. V. Baires V. B. Ivanov B. E. Ivanov S. S. Krokhina Yu. Ya. Efremov R. L. Korshunov |
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| Affiliation: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions The reaction of dimethylaminomethyl derivatives Me2NCH2X with dimethyl sulfite proceeds by analogy with the Arbuzov rearrangement under mild conditions. The yield of the rearrangement product increases with increasing nueleophilicity of (X).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.1, pp. 220–223, January, 1986. |
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