|
|||||
|
|
| 三唑酮氯化锌配合物的合成和晶体结构研究 | |
| 引用本文： | 张培志,吴 军,龚钰秋,胡秀荣,顾建明. 三唑酮氯化锌配合物的合成和晶体结构研究[J]. 无机化学学报, 2003, 19(7): 753-756 |
| 作者姓名： | 张培志 吴 军 龚钰秋 胡秀荣 顾建明 |
| 作者单位： | 1. 浙江科技学院生物与化学工程学系,杭州,310012 2. 浙江大学化学系,杭州,310027 3. 浙江大学分析测试中心,杭州,310028 |
| 基金项目： | 浙江省自然科学基金资助项目(No.201004)，浙江省教育厅基金资助项目(No.20010436)。 |
| 摘 要： | The new compound was synthesized by the reaction of ZnCl2 and triadimefon(ratio 1∶2) in ethanol solution refluxing for 6 hours. The crystal used for X-ray analysis was obtained by slow evaporation of the solution at room temperature. It crystallizes in the monoclinic system, space group P2/n. The lattice parameters are: a=1.58916(6)nm, b=0.60634(2)nm, c=1.83566(8)nm, β=93.979(2)°, V=1.7645(1)nm3, Z=2, Dc=1.362g·cm-3, F(000)=744.00, μ(Mo Kα)=1.038mm-1, R1=0.042, wR2=0.106. In the complex, the Zn(Ⅱ) cation is tetrahedrally coordinated to two triadimefon ligands and two chloride in cis disposition. The title complex was also characterized by elemental analysis, molar conductance, IR and TG-DTA. CCDC: 207413. |
| 关 键 词： | 三唑酮 锌(Ⅱ)配合物 合成 晶体结构 |
| 修稿时间： | 2003-03-12 |
Synthesis and Crystal Structure of the Complex of Triadimefon and Zinc Chloride |
|
| ZHANG Pei-Zhi,WU Jun,GONG Yu-Qiu,HU Xiu-Rong and GU Jian-Ming. Synthesis and Crystal Structure of the Complex of Triadimefon and Zinc Chloride[J]. Chinese Journal of Inorganic Chemistry, 2003, 19(7): 753-756 | |
| Authors: | ZHANG Pei-Zhi WU Jun GONG Yu-Qiu HU Xiu-Rong GU Jian-Ming |
| Affiliation: | Department of Biological and Chemical Engineering, Zhejiang University of Science and Technology, Hangzhou 310012,Department of Chemistry, Zhejiang University, Hangzhou 310027,Department of Chemistry, Zhejiang University, Hangzhou 310027,The Central Laboratory, Zhejiang University, Hangzhou 310028 and The Central Laboratory, Zhejiang University, Hangzhou 310028 |
| Abstract: | |
| Keywords: | |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |
| 点击此处可从《无机化学学报》浏览原始摘要信息 | |
| 点击此处可从《无机化学学报》下载全文 | |