| SYNTHESES AND PROPERTIES OF SOME ORGANOSILANE POLYMERS |
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| 引用本文： | 张兴华,Robert West. SYNTHESES AND PROPERTIES OF SOME ORGANOSILANE POLYMERS[J]. 高分子科学, 1984, 0(1): 92-104 |
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| 作者姓名： | 张兴华 Robert West |
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| 作者单位： | Institute of Chemistry，Academia Sinica，Beijing，Department of Chemistry，University of Wisconsin，Madison，WI 53706 U.S.A. |
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| 摘 要： | Some organosilane polymers with high molecular weights have been synthesized by cocondensztion of organosilicon dihalide monomers with sodium metal in toluene. These polymers are both soluble in common solvents and meltable at lower temperatures, and can be molded, cast into films or drawn into fibers. Exposure of the solid polymers to ultraviolet light leads to degradation or crosslinking.
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| 收稿时间： | 1983-08-26 |
SYNTHESES AND PROPERTIES OF SOME ORGANOSILANE POLYMERS* |
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| ZHANG Xinghua,Robert West. SYNTHESES AND PROPERTIES OF SOME ORGANOSILANE POLYMERS*[J]. Chinese Journal of Polymer Science, 1984, 0(1): 92-104 |
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| Authors: | ZHANG Xinghua Robert West |
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| Affiliation: | Institute of Chemistry; Academia Sinica; Beijing; Department of Chemistry; University of Wisconsin; Madison; WI 53706 U.S.A. |
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| Abstract: | Some organosilane polymers with high molecular weights have been synthesized by cocondensztion of organosilicon dihalide monomers with sodium metal in toluene. These polymers are both soluble in common solvents and meltable at lower temperatures, and can be molded, cast into films or drawn into fibers. Exposure of the solid polymers to ultraviolet light leads to degradation or crosslinking. |
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