Matrix-isolated NCl. Radiative rates for b Π→a Δ, b Σ→X Σ and a Δ→X Σ in solid argon |
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Authors: | A C Becker and Ulrich Schurath |
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Institution: | Institut für Physikalische Chemieder Universität Bonn, Wegelerstrasse 12, D-5300 Bonn, Federal Republic of Germany |
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Abstract: | Radiative rates for the b→a, b→X, and a→X transitions in NCl have been determined in solid argon. The rates - corrected for the refractive index - are 520, 260, and 0.27 s?1. The b→X and a→X rates are in good agreement with calculated rates, whereas the b→a rate is enhanced by five orders of magnitude in the matrix. |
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