Crystal structure oftrans-tetrachlorobis[2-(2-1H-imidazolyl)-1H-imidazolium]cadmium(II), [Cd(H3biim)2Cl4] |
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| Authors: | Colin Hester Russell G Baughman Harvest Collier |
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| Institution: | (1) Department of Chemistry, University of Missouri-Rolla, 65401 Rolla, Missouri;(2) Division of Science, Northeast Missouri State University, 63501 Kirksville, Missouri |
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| Abstract: | The reaction between cadmium(II) chloride and 2,2'-bi-1H-imidazole (H2biim) in an acidic solution affords Cd(H3biim)2Cl4] (H3biim=2-(2-1H-imidazolyl)-1H-imidazolium) in 63% yield. The compound crystallizes in the triclinic space groupP1, wherea=8.072(2),b=8.100(2),c=8.593(2) Å,  =75.89(2),  =62.94(2),  =63.29(1)°,V=446.4(2) Å3, andZ=1. The central Cd atom exhibits an octahedral geometry composed of a Cl4N2 core. The Cd-N bond distance is 2.392(2) Å. Cd–Cl distances are 2.5919(9) and 2.671(1) Å. |
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| Keywords: | Crystal structure 2 2'-bi-1H-imidazole cadmium chloride |
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