| 相分离聚合法:(Ⅰ)羧酸型共聚功能微球的合成 |
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| 引用本文： | 王身国,蒋文辉,张晓琴,曾玉华,何树平,袁瑞红.相分离聚合法:(Ⅰ)羧酸型共聚功能微球的合成[J].高分子学报,1992,0(3):368-371. |
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| 作者姓名： | 王身国 蒋文辉 张晓琴 曾玉华 何树平 袁瑞红 |
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| 作者单位： | 中国科学院化学研究所 100080 |
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| 摘 要： |
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| 关 键 词： | 相分离聚合 高分子微球 羧酸基 |
| 收稿时间： | 1991-06-18 |
PHASE-SEPARATED POLYMERIZATION (I) SYNTHESIS OF FUNCTIONAL MICROSPHERES WITH CARBOXYLIC GROUP |
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| WANG Shen-guo,JIANG Wen-hui,ZHANG Xiao-qin,ZENG Yu-hua,HE Shu-ping,YUAN Rui-hong.PHASE-SEPARATED POLYMERIZATION (I) SYNTHESIS OF FUNCTIONAL MICROSPHERES WITH CARBOXYLIC GROUP[J].Acta Polymerica Sinica,1992,0(3):368-371. |
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| Authors: | WANG Shen-guo JIANG Wen-hui ZHANG Xiao-qin ZENG Yu-hua HE Shu-ping YUAN Rui-hong |
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| Institution: | Institute of Chemistry; Academia Sinica; Beijing; Post code: 100080 |
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| Abstract: | Crosslinked functional microspheres with Carboxylic group have been synthesized by the method of Phaseseparated polymerization from monomers of methacrylic acid and other vinyl-type monomers. The effects of reaction condition such as comonomer, crosslinking agent, initiator and polymerization temperature, as well as polymerization time on the morphological structure of microspheres formed have been studied. The functional polymeric microspheres with good spherical form, diameter near 5 micrometers, narrow dispersion in diameter and contained carboxylic group can be synthesized stably. |
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