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Reactions involving fluoride ion. Part 40. Amines as initiators of fluoride ion catalysed reactions |
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| Authors: | Richard D. Chambers William K. Gray Stewart R. Korn |
| Affiliation: | aDepartment of Chemistry. University of Durham, South Road. Durham. DH1 3LE, USA bZeneca Specialities, Leeds Road, Huddersfield. HD2 1FF, USA |
| Abstract: | Tetrakis(dimethylamino)ethene (TDAE) and trimethylamine react with anhydrous unsaturated fluorocarbons to produce, ‘in situ’, powerful fluoride- ion sources. These are used to initiate carbon- carbon bond forming reactions eg. oligomerisation and polyfluoroalkylation, and many of these reactions occur efficiently in the absence of a solvent. |
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