Synthesis,Structure, and Conduction of Trisubstituted Cesium and Rubidium Salts of Trimesic Acid |
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| Authors: | Pisareva A. V. Dobrovolsky Yu. A. Shilov G. V. Karelin A. I. |
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| Affiliation: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, Institutskii pr. 16, Chernogolovka, Moscow oblast, 142432, Russia |
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| Abstract: | Salts of trimesic (1,3,5-benzenetricarboxylic) acid generally formulated as   3[C6H3(COO)3] · 5H2O, where Me = Rb and Cs, are synthesized and their structure and conductivity are examined. Both salts are ionic conductors with conductivities of 4.6 × 10–7 and 2.2 × 10–9  –1 cm–1 at 298 K and activation energies of conduction equal to (1.09 ± 0.02) and (1.07 ± 0.01) eV, respectively. |
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