Photoinitiated Reaction of β-Bromonaphthalene with Pinacolone Ion in DMSO |
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作者单位: | Department of Chemistry,University of Shanxi,Taiyuan,Shanxi 030006 |
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基金项目: | the Returned Student Science Foundation of Shanxi Province of China. |
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摘 要: | The radical nucleophilic substitution reaction (SRN1) has been studied widely. The reaction has constituted an important synthetic possibility to achieve substitution of different substrates with different nucleophiles1-3. The main steps of the reaction process are presented in Scheme 1.Scheme 1. Pinacolone enolate ions are widely used as nucleophiles within SRN1reaction 4-6 because it can introduce six carbon atoms into substitution products. In the paper, the photoinitiated reaction of …
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关 键 词: | β-bromonaphthalene |
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