| Selective formation of luminescent chiral cocrystal: Molecular self-assembly of 2,2′-binaphthol and 2-(3-pyridyl)-1H-benzimidazole |
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| 作者姓名： | Yanluo Lu Yanqun Tang Heyang Lin Xiaoyu Fang Bo Lu Dan Li Dongpeng Yan |
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| 作者单位： | a State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
b Key Laboratory of Theoretical and Computational Photochemistry, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China (NSFC, Nos. 21771021 and 21473013), the National Basic Research Program of China (973 Program, No. 2014CB932103), and Beijing Municipal Natural Science Foundation (No. 2152016). |
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| 摘 要： | Luminescent chiral cocrystal based on the self-assembly of 2,2'-binaphthol and 2-(3-pyridyl)-1H-benzimidazole (P.) has been developed, in which 100% R configuration of BINOL can be obtained in the cocrystal products. The final structure presents the same P.R. The studies suggested that the cocrystallization approach could have much flexibility and potential applications for the design of chiral fluorescent materials.
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| 收稿时间： | 22 November 2017 |
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