| Silver(Ⅱ) 5,10,15,20-tetra(ethoxycarbonyl) porphyrin:An unexpected six-coordinate linear assembled structure |
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| 引用本文： | Hua-Hua Wang,Hai-Yang Liu,Fan Cheng,Atif Ali,Lei Shi,Xin-Yan Xiao,Chi-Kwong Chang. Silver(Ⅱ) 5,10,15,20-tetra(ethoxycarbonyl) porphyrin:An unexpected six-coordinate linear assembled structure[J]. 中国化学快报, 2018, 29(9): 1404-1408. DOI: 10.1016/j.cclet.2017.12.027 |
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| 作者姓名： | Hua-Hua Wang Hai-Yang Liu Fan Cheng Atif Ali Lei Shi Xin-Yan Xiao Chi-Kwong Chang |
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| 作者单位： | a School of Chemistry and Chemical Engineering, Key Laboratory of Functional Molecular Engineering of Guangdong Province, South China University of Technology, Guangzhou 510641, China;b Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China;c Department of Chemistry, Guangdong University of Education, Guangzhou 510303, China;d Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA |
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| 基金项目： | We gratefully acknowledge financial support from the National Natural Science Foundation of China (Nos. 21371059, 21376099, 21671068). |
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| 摘 要： | A novel six-coordinated silver porphyrin linear assembly was observed in silver(II) 5,10,15,20-tetra(ethoxycarbonyl) porphyrin crystal.
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| 收稿时间： | 2017-09-30 |
Silver(II) 5,10,15,20-tetra(ethoxycarbonyl) porphyrin: An unexpected six-coordinate linear assembled structure |
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| Hua-Hua Wang,Hai-Yang Liu,Fan Cheng,Atif Ali,Lei Shi,Xin-Yan Xiao,Chi-Kwong Chang. Silver(II) 5,10,15,20-tetra(ethoxycarbonyl) porphyrin: An unexpected six-coordinate linear assembled structure[J]. Chinese Chemical Letters, 2018, 29(9): 1404-1408. DOI: 10.1016/j.cclet.2017.12.027 |
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| Authors: | Hua-Hua Wang Hai-Yang Liu Fan Cheng Atif Ali Lei Shi Xin-Yan Xiao Chi-Kwong Chang |
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| Affiliation: | a School of Chemistry and Chemical Engineering, Key Laboratory of Functional Molecular Engineering of Guangdong Province, South China University of Technology, Guangzhou 510641, China;b Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, China;c Department of Chemistry, Guangdong University of Education, Guangzhou 510303, China;d Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA |
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| Abstract: | The crystal structure of silver(II) 5,10,15,20-tetra(ethoxycarbonyl)porphyrin (Ag[II]TECP) revealed it formed a one-dimensional coordination polymer through weak Ag–O interactions with an unusual six-coordinated central silver(II) atom. |
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| Keywords: | Porphyrin Silver Six-coordinated assembly Crystal structure Hydrogen bond |
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