Vibrational coupling in collision-induced raman scattering |
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| Authors: | R Ouillon W Holzer |
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| Institution: | Département de Recherches Physiques, Laboratoire Associé au C.N.R.S. no. 71, Université P. et M Curie, 75230 Paris Cedex 05, France;Groupe de Physique des Solides de l''E.N.S., Laboratoire associé au C.N.R.S., Université Paris VII, 75221 Paris Cedex 05, France |
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| Abstract: | The observed splitting of the collision-induced Raman band v3 in liquid SF6 is interpreted as vibrational exciton line splitting The bandwidth of the collision-induced Raman bands v3 and v6, in liquid SF6 and v2 and v3 in liquid CO2 and CS2 can be explained by contributions from reonentational motion and from transition dipole-transition dipole vibrational coupling. |
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| Keywords: | Present address: G S F -B P T D-8000 Munich West Germany |
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