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Thermodtnamics of surfactant-polymer interactions in dilute aqueous solutions
Authors:R. Nagarajan
Affiliation:Department of Chemistry Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802.USA
Abstract:A thermodynamic model for suffactant binding to polymers in dilute aqueous solution is present. It assumes that the inter- molecular contacts between the polar and the non-polar polymer segment resemble the macroscopic hydrocarbon-water interface ,where preferential accumulation of surfactant accurs. The model also considers the competitive surfactant micelization.
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