Fluorescence quenching of pyrene and pyrenedecanoic acid by various kinds of N,N-dialkylanilines in dipalmitoylphosphatidylcholine liposomes |
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Authors: | Koji Kano Hirofumi Kawazumi Teiichiro Ogawa Junzo Sunamoto |
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Affiliation: | Department of Molecular Science and Technology, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812, Japan;Department of Industrial Chemistry, Faculty of Engineering, Nagasaki University, Nagasaki 852, Japan |
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Abstract: | Fluorescence quenching of pyrene and pyrenedecanoic acid by various kinds of anilines has been studied in dipalmitoylphosphatidylcholine liposomes in gel phases. N,N-dimethylaniline and p-isopropyl-N,N-dimethylaniline caused anisotropic diffusional quenching, while N,N-dicetylaniline, a less mobile quencher, predominantly caused static quenching. These data suggested the location sites of both pyrenes and anilines in the membranes. |
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