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A crucial demonstration of strong collisional behavior of vibrational energy for gas-surface collisions
Authors:M.C. Flowers  F.C. Wolters  D.F. Kelley  B.S. Rabinovitch
Affiliation:Department of Chemistry BG-10, University of Washington, Seattle, Washington 98195, USA
Abstract:Application of the variable encounter method (VEM) has been made to the thermal cyclobutene decomposition system. Vibrational energy transfer in the cyclobutene-seasoned quartz surface system has been studied. The occurrence of strong collisions is demonstrated in crucial manner at temperatures below 400 K.
Keywords:Permanent address: University of Southampton   Southampton   UK.
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