Renewable benzoxazine monomer from Vanillin: Synthesis,characterization, and studies on curing behavior |
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| Authors: | N. K. Sini Jayashree Bijwe Indra K. Varma |
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| Affiliation: | 1. Industrial Tribology Machine Dynamics and Maintenance Engineering Centre, Indian Institute of Technology Delhi, , New Delhi, 110 016 India;2. Centre for Polymer Science and Engineering, Indian Institute of Technology Delhi, , New Delhi, 110 016 India |
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| Abstract: | A novel renewable based benzoxazine, 3‐(furan‐2‐ylmethyl)?8‐methoxy‐3,4‐dihydro‐2H‐1,3‐benzoxazine‐6‐formyl (Va‐Bz), has been synthesized from a lignin derived chemical “vanillin” without solvents. Poly (Va‐Bz) has high Tg and excellent thermal and adhesive properties. A mechanism of cross‐linking, due to electrophilic substitution at furan and decarboxylation of carboxylic group of benzene ring, is suggested. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 7–11 |
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| Keywords: | adhesives polybenzoxazines renewable resources thermal properties |
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