| 对O'Driscoll的离子共聚理论的商榷 |
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| 引用本文： | 胡群华,郭少华,应圣康. 对O'Driscoll的离子共聚理论的商榷[J]. 高分子学报, 1989, 0(4): 472-476 |
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| 作者姓名： | 胡群华 郭少华 应圣康 |
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| 作者单位： | 华东化工学院高分子材料研究所 上海(胡群华，郭少华)，华东化工学院高分子材料研究所 上海(应圣康) |
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| 基金项目： | 中国自然科学基金委员会资助项目 |
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| 摘 要： | <正> Mayo和Lewis建立了二元共聚合反应共聚组成方程式,并引出了竞聚率概念。自从Szwmc发现“活性聚合物”以来,人们在研究非极性溶剂中阴离子共聚时,常发现有符合“理想”共聚ν_1·ν_2=1的实验结果,O’2Driscoll和Kuntz用过渡状态理论,提出活性种之间的反应能力差异X倍,用此来调和理论与实验结果的矛盾。本文对O’Driscoll理论进行了修正和完善,并从活性种之间的相互缔合作用对聚合反应的影响
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| 关 键 词： | α-甲基苯乙烯 阴离子 共聚合 |
| 收稿时间： | 1987-09-30 |
COMMENTS ON O''''DRISCOLL THEORY OF IONIC COPOLYMERIZATION |
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| HU Qun-hua,GUO Shao-hua,YING Sheng-kang. COMMENTS ON O''''DRISCOLL THEORY OF IONIC COPOLYMERIZATION[J]. Acta Polymerica Sinica, 1989, 0(4): 472-476 |
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| Authors: | HU Qun-hua GUO Shao-hua YING Sheng-kang |
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| Affiliation: | East China University of Chemical Technology; Shanghai |
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| Abstract: | The relationship between ideal copolymerizating behavior and the nature of reactive species of anionic copolymerization in nonpolar solvent has been inherently analyzed. The quantitative expression of in O'Driscoll-Kuntz theory has been unambiguously exploited and elucidated. It is postulated that system of anionic copolymerization in nonpolar solvent becomes "ideal" copolymerization system, only if reactive species coexist in dimeric and monomeric. Only in these cases O'Driscoll-Kuntz theory is adaptable. |
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| Keywords: | Alpha-methylstyrene Styrene Anionic Copolymerization |
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