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A theoretical study of the barbier reaction |
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| Authors: | Albert Moyano Miquel A. Perica s Antoni Riera Jean-Louis Luche |
| Affiliation: | aDepartament de Qui´mica Orga´nica, Universitat de Barcelona, c/ Martf i Franque´s, 1-11. 08028-Barcelona, Spain bLEDSS, Universite´J. Fourier, BP 53X, 38041 Grenoble, France. |
| Abstract: | Semiempirical MO calculations are shown to provide a more detailed picture of the radical ion mechanism of the Barbier reaction in the general case. Calculated electron affinities give a clue for its extension to other cases. |
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