Reactions of dichloro-substituted iron(ii) clathrochelate with 1,4-dioxane radical derivatives: synthesis, structure, and spectral characteristics of the dioxane ring opening product in the ribbed fragment of the macrobicyclic ligand |
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| Authors: | M. A. Vershinin A. B. Burdukov Z. A. Starikova V. V. Novikov Ya. Z. Voloshin |
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| Affiliation: | 1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Lavrent??eva, 630090, Novosibirsk, Russian Federation
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
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| Abstract: | A free-radical substitution for the chlorine atoms with the 1,4-dioxan-2-yl fragment in the tris-dichloro-substituted dioximate iron(II) clathrochelate is accompanied by the oxidative dioxane ring opening as a side process. The compound obtained was characterized by elemental analysis data, 1D and 2D 1H and 13C{1H} NMR spectroscopy (in solution), MALDI TOF mass spectrometry, as well as by single-crystal X-ray diffraction. |
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