Synthesis of (5S*,4aS*,7aS*)-5-hydroxyhexahydro-cyclopenta[c]pyran-3(1H)-one |
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| Authors: | A V Lozanova A O Chizhov V V Veselovsky |
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| Institution: | 1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
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| Abstract: | (5S*,4aS*,7aS*)-5-Hydroxyhexahydrocyclopentac]pyran-3(1H)-one, the promising isoprostane building block, was synthesized using intramolecular 3+2] cycloaddition of silyl nitronate generated from 4-benzyloxy-3-nitroocta-2,7-diene on the key step. |
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