Binuclear heterometallic {M-Ln} pivalate complexes (M = Co, Ni, Cu; Ln = Sm, Gd): synthesis, structure, and thermolysis |
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| Authors: | E V Orlova A E Goldberg M A Kiskin P S Koroteev A L Emelina M A Bykov G G Aleksandrov Zh V Dobrokhotova V M Novotortsev I L Eremenko |
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| Institution: | 1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation
2. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation
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| Abstract: | Binuclear heterometallic complexes (??2-bpy)CoLn(Piv)5(H2O), (??2-bpy)NiLn(Piv)5(H2O), and (??2-bpy)CuLn(Piv)5(HPiv) (Ln = Sm or Gd, Piv- is the pivalate anion) were synthesized. A comparative study of the structural characteristics and the thermolysis of the resulting compounds was performed. |
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