The use of carboranylphosphite ligands in Rh-catalyzed hydroformylation of alkenes in supercritical carbon dioxide |
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| Authors: | S E Lyubimov P V Petrovskii E A Rastorguev T A Verbitskaya V N Kalinin V A Davankov |
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| Institution: | 1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
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| Abstract: | Novel carborane-containing phosphites were synthesized. The efficiency of the ligands was tested in the Rh-catalyzed hydroformylation of styrene, hept-1-ene, and oct-1-ene in super-critical carbon dioxide (scCO2) and toluene. The use of scCO2 as the reaction medium allows one to attain higher conversions and regioselectivities compared to toluene. |
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