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Synthesis and structure elucidation of oxidative coupling products of 2-hydroxy-1,4-naphthoquinones
Authors:A Ya Yakubovskaya  T Yu Kochergina  V A Denisenko  D V Berdyshev  V P Glazunov  V Ph Anufriev
Institution:(1) Pacific Institute of Bioorganic Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022 Vladivostok, Russian Federation
Abstract:2,3-Dihydro-3-O-(1,4-naphthoquinon-2-yl)-2-oxo-1,4-naphthoquinones are the products of oxidative coupling of substituted 2-hydroxy-1,4-naphthoquinones (regardless of the presence of peri-hydroxy groups in their structures) under the action of lead dioxide. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 294—298, February, 2006.
Keywords:2-hydroxy-1  4-naphthoquinone  2  5(8)-dihydroxy-1  4-naphthoquinone  2  5  8-trihydroxy-1  4-naphthoquinone  lead dioxide  oxidative coupling  2  3-dihydro-3-O-(1  4-naphthoquinon-2-yl)-2-oxo-1  4-naphthoquinone  density functional theory
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