Cis double allylation of cyclopropenes using cyclopropylindium reagents |
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| Authors: | Hirashita Tsunehisa Shiraki Fumio Onishi Kenji Ogura Mamiko Araki Shuki |
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| Institution: | Omohi College, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan. hirasita@nitech.ac.jp |
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| Abstract: | The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et(2)Zn and Et(3)Al), giving the corresponding cis-diallylcyclopropanes in high yields. |
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