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An unprecedented heterotrimetallic Fe/Cu/Co core for mild and highly efficient catalytic oxidation of cycloalkanes by hydrogen peroxide
Authors:Nesterov Dmytro S  Kokozay Volodymyr N  Dyakonenko Viktoriya V  Shishkin Oleg V  Jezierska Julia  Ozarowski Andrew  Kirillov Alexander M  Kopylovich Maximilian N  Pombeiro Armando J L
Institution:Depart. Inorg. Chemistry, National Taras Shevchenko Univ., Volodymyrska str. 64, Kyiv, 01033, Ukraine.
Abstract:An unprecedented hexanuclear heterotrimetallic Fe/Cu/Co complex bearing two Cu(mu-O)2Co(mu-O)2Fe cores is easily prepared by self-assembly and acts as a remarkable catalyst for the peroxidative oxidation of cycloalkanes under mild conditions.
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