| 稀土—4—（2—吡啶偶氮）间苯二酚螯合物的高效液相色谱分离和测定 |
| |
| 引用本文： | 高锦章 王继敏. 稀土—4—（2—吡啶偶氮）间苯二酚螯合物的高效液相色谱分离和测定[J]. 高等学校化学学报, 1991, 12(2): 169-172 |
| |
| 作者姓名： | 高锦章 王继敏 |
| |
| 作者单位： | 西北师范大学化学研究所 730070(高锦章，王继敏，胡平)，西北师范大学化学研究所 730070(白光弼) |
| |
| 摘 要： | 本文讨论了反相离子对液相色谱法分离和检测稀土-4-(2-吡啶偶氮)间苯二酚螯合物的各种条件,在12 min内完成了9种稀土螫合物的分离,校正曲线的线性范围是(ppm):La(0.01～3.20),Ce(0.03～2.8),Pr(0.06～3.5),Nd(0.05～3.8),Sm(0.01～3.0),Eu(0.05～3.4),Tb(0.02～3.0),Ho(0.01～3.4),Er(0.06～4.0).变异系数小于1.2％.
|
| 关 键 词： | 稀土元素 PAR 螯合物 高效液相色谱 |
Separation and Determination of Rare Earth Chelates by High PerformanceLiquid Chromatography Using 4-(2-Pyridylazo) Resorcinolas Chromophoric Reagent |
| |
| Gao Jin-zhang,Wang Ji-min,Hu Ping,Bai Guang-bi. Separation and Determination of Rare Earth Chelates by High PerformanceLiquid Chromatography Using 4-(2-Pyridylazo) Resorcinolas Chromophoric Reagent[J]. Chemical Research In Chinese Universities, 1991, 12(2): 169-172 |
| |
| Authors: | Gao Jin-zhang Wang Ji-min Hu Ping Bai Guang-bi |
| |
| Abstract: | A method for separation and determination of nine lanthanides chelates in 12 min by using reversed phase ion pair high performance liquid chromatography with 4- (2-pyridylazo) resercinol (PAR) as the chromophoric reagent has been studied. The optimum condition of separation and determination are also described in this paper. The calibration curve is a linear function of concentration in the range of 0. 01 -3. 0 ppm for La, 0. 03-2. 8 ppm for Ce, 0. 06-3. 50 ppm for Nd, 0. 05-3. 8 ppm for Pr, 0. 01 -3. 0 ppm for Sm, 0. 05-3. 40 ppm for Eu, 0. 02-3. 0 ppm for Tb, 0. 01 -3. 4 ppm for Ho and 0. 02- 4. 00 ppm for Er. The variational coefficient is found to be less than |
| |
| Keywords: | Separation and determination of rare earths Reversed phase ion pair high performance liquid chromatography 4-(2-pyridylazo) resercinol |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
