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Spectral band assignments for Cu+ in alkali halides via two-color two-photon spectroscopy
Authors:Ring-Ling Chien
Institution:Deparment of Chemistry, Princeton University, Princeton, New Jersey 08544, USA
Abstract:A strong beam + weak beam two-color two-photon spectroscopy was used to obtain spectra from the interconfiguration transition d10 → d9s of Cu+ impurity in some alkali halide hosts. The selection rules for two counterpropagating beams independent choice of polarizations to obtain pure Eg and T2g bands are also given. The results show better agreement with theoretical calculations than that front single beam arrangement.
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