Absorption and emission spectra of molecules subject to hindered internal rotation with an application to α-dicarbonyls |
| |
| Authors: | M. Pawlikowski M.Z. Zgierski G. Orlandi |
| |
| Affiliation: | Division of Chemistry, National Research Council of Canada, Ottawa, Canada K1A 0R6;Istituto Chimico “G. Ciamician”, Universitá di Bologna, Bologna, Italy |
| |
| Abstract: | A simple model of a flexible molecule with one hindered rotation and one totally symmetric vibration is presented and the resulting absorption and emission spectra are discussed. The results are applied to 1S0-1S1(1nπ*) spectra of α-dicarbonyls. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
