Surface enhanced raman spectroscopy of the non-aqueous system silver/acetonitrile,KSCN |
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Authors: | DA Guzonas GF Atkinson DE Irish |
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Institution: | Guelph-Waterloo Centre for Graduate work in Chemistry, Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1 |
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Abstract: | The ν1(CN) band of SCN? in acetonitrile solvent has been observed, surface enhanced, at a silver electrode. Adsorption through the S of SCN? is suggested. The changes of frequency and intensity with the change of electrode potential are reported. The υ(CN) band of the solvent is also probably enhanced. |
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