Alkali—SCl2 chemiluminescence: Vibrational population inversion in the B state of S2 |
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| Authors: | J.J. Wright L.C. Balling |
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| Affiliation: | Department of Physics, University of New Hampshire, Durham, New Hampshire 03824, USA |
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| Abstract: | S2(B-X) chemiluminescence, primarily from ν′ = 0 and 1, has been observed in alkali atom—SCl2 reactions. The addition of He or Ar buffer gas to the reaction chamber alters the reaction dynamics, and at certain buffer gas pressures the S2 emission originates exclusively from the ν′ = 6–9 vibrational levels of the B(3Σu?) state. |
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