Mode-to-mode vibrational energy transfer in D2CO: Evidence of coriolis-enhanced rotational selectivity |
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| Authors: | J.G. Haub B.J. Orr |
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| Affiliation: | School of Chemistry, The University of New South Wales, Sydney, N.S.W. 2033, Australia |
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| Abstract: | Infrared—ultraviolet double resonance spectroscopy is used to demonstrate rapid collision-induced V-V transfer between the v6 and v4 vibrational manifolds of D2CO. The rate of transfer is at least gas-kinetic and is explained in terms of Coriolis coupling and rotationally specific, quasi-resonant relaxation channels |
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