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Quencing of perylene fluorescence by Ag+ ions via exciplex formation
Authors:H. Dreeskamp  A. Laufer  M. Zander
Affiliation:Institut für Physikalische und Theoretische Chemie der Technischen Universität, Hans Sommer Strasse 10, D-3300 Braunschweig, West Germany;Rütgerswerke AG, D-4620 Castrop-Rauxel, West Germany
Abstract:The fluorescence of perylene in alcoholic solution is dynamically quenched by AgClO4 resulting in a new emission band with its maximum around 480 nm. Analysis of fluorescence decay curves at various emission wavelengths proves the formation of a perylene/Aa+ ion exciplex in the quenching reaction.
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