Quencing of perylene fluorescence by Ag+ ions via exciplex formation |
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Authors: | H. Dreeskamp A. Laufer M. Zander |
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Affiliation: | Institut für Physikalische und Theoretische Chemie der Technischen Universität, Hans Sommer Strasse 10, D-3300 Braunschweig, West Germany;Rütgerswerke AG, D-4620 Castrop-Rauxel, West Germany |
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Abstract: | The fluorescence of perylene in alcoholic solution is dynamically quenched by AgClO4 resulting in a new emission band with its maximum around 480 nm. Analysis of fluorescence decay curves at various emission wavelengths proves the formation of a perylene/Aa+ ion exciplex in the quenching reaction. |
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