Laser photodissociation of PuF6 and transient product absorption in the visible |
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| Authors: | K.C. Kim G.M. Campbell |
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| Affiliation: | Materials Science and Techonology, Division, Los, Alamos National Laboratory, Box 1663, MS E505, Los Alamos, New Mexico 87545, USA |
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| Abstract: | PuF6 moleculs were flash-photolyzed in a static cell at 248 nm using a KrF excimer laser. The absorption by the transient product was detected in the wavelength region of 500–850 nm by probing the photolysis volume coaxially with a cw source. A measurement of the product absorption cross section at 632.8 nm is shown. The product absorption decay is discussed in terms of primary photolytic reactions among the product species. |
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