Assignment of π → 3d rydberg transitions in ethylene around 9 eV using MCD and synchrotron radiation |
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| Authors: | PA Snyder PN Schatz EM Rowe |
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| Institution: | Department of Chemistry, Florida Atlantic University, Boca Raton, Florida 33431, USA;Department of Chemistry, University of Virginia, Charlottesville, Virginia 22901, USA;Synchrotron Radiation Center, University of Wisconsin—Madison, Physical Sciences Laboratory, Stoughton, Wisconsin 53589, USA |
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| Abstract: | Magnetic circular dichroism measurements on ethylene are reported over the region of the 3R00 and 4R00? origins around 9 eV. The results show conclusively that each origin is a composite of two electronic transitions. The 3R00 origin is assigned to the Rydberg transitions, tA1 → 1B2(3dδ) + 1B3(3dδ). 4R00? is assigned as 1A1 → 3R00 + ν3(u). |
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