| Reaction of Perfluoroalkanesulfinyl Chlorides with Enamines: A Facile Synthesis of α-Perfluoroalkanesulfinyl Ketones and Aldehydes |
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| 作者姓名： | LI Xiaobo CHEN Lingjun WANG Xiaojin LIU Jintao |
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| 作者单位： | Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, ;Chinese Academy of Sciences, Shanghai 200032, China ; |
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| 摘 要： | The reaction of perfluoroalkanesulfinyl chlorides with enamines was achieved in the presence of triethylamine, and α-perfluoroalkanesulfinyl carbonyl compounds were obtained in moderate to good yields after hydrolysis of the reaction intermediates with dilute hydrochloric acid.
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| 关 键 词： | perfluoroalkanesulfinyl chloride enamine α-perfluoroalkanesulfinyl carbonyl compound triethylamine hydrolysis |
| 收稿时间： | 2008-11-27 |
| 修稿时间： | 2008-12-15 |
Reaction of Perfluoroalkanesulfinyl Chlorides with Enamines: A Facile Synthesis of α-Perfluoroalkanesulfinyl Ketones and Aldehydes |
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| LI Xiaobo,CHEN Lingjun,WANG Xiaojin,LIU Jintao.Reaction of Perfluoroalkanesulfinyl Chlorides with Enamines: A Facile Synthesis of α-Perfluoroalkanesulfinyl Ketones and Aldehydes[J].Chinese Journal of Chemistry,2009,27(1):151-156. |
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| Authors: | LI Xiaobo CHEN Lingjun WANG Xiaojin LIU Jintao |
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| Institution: | Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | The reaction of perfluoroalkanesulfinyl chlorides with enamines was achieved in the presence of triethylamine, and α‐perfluoroalkanesulfinyl carbonyl compounds were obtained in moderate to good yields after hydrolysis of the reaction intermediates with dilute hydrochloric acid. |
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| Keywords: | perfluoroalkanesulfinyl chloride enamine α‐perfluoroalkanesulfinyl carbonyl compound triethylamine hydrolysis |
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