Isolation of a stable 1-iridabicyclo[3.2.0]hepta-1,3,6-triene and its reversible transformation into an iridacycloheptatriene |
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| Authors: | Paneque Margarita Poveda Manuel L Rendón Nuria Mereiter Kurt |
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| Affiliation: | Instituto de Investigaciones Químicas, Consejo Superior de Investigaciones Científicas (CSIC)-Universidad de Sevilla, Avenida Américo Vespucio s/n, Isla de la Cartuja, 41092 Seville, Spain. paneque@iiq.csic.es |
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| Abstract: | Reaction of the iridacyclopentadiene complex 2 with 2-butyne yields a mixture in equilibrium of the iridacycloheptatriene 3 and a novel 1-iridabicyclo[3.2.0]hepta-1,3,6-triene, 4. |
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