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离子液体的制备及应用*
引用本文:张晓春,张锁江,左勇,赵国英,张香平.离子液体的制备及应用*[J].化学进展,2010,22(7):1499-1508.
作者姓名:张晓春  张锁江  左勇  赵国英  张香平
作者单位:( 中国科学院过程工程研究所 多项复杂系统国家重点实验室 北京 100190 )
基金项目:国家杰出青年科学基金;国家重点基础研究发展计划(973)
摘    要:离子液体由于具有独特的物理化学性质而成为一种新型的绿色溶剂,近年来成为国际上研究的前沿和热点。它为开发新型绿色工艺、实现传统重污染、高能耗工业过程的升级换代提供了新机遇。本文介绍了离子液体的合成与制备方法,以及离子液体在CO2捕集分离及转化利用、电解/电镀铝、SO2吸收、废水处理以及废旧塑料降解循环利用中的应用,展望了离子液体的发展前景。

关 键 词:离子液体  制备  应用  绿色化学  清洁过程  
收稿时间:2010-03-22

Preparation and Applications of Ionic Liquids
Zhang Xiaochun ZhangSuojiangZuoYong Zhao Guoyang ZhangXiangping.Preparation and Applications of Ionic Liquids[J].Progress in Chemistry,2010,22(7):1499-1508.
Authors:Zhang Xiaochun ZhangSuojiangZuoYong Zhao Guoyang ZhangXiangping
Institution:( State key Laboratory of Multiphase Complex Systems, Institute of Process Engineerting, Chinese Academy of Sciences, Beijing 100190, China )
Abstract:Ionic liquids are a new type of green solvents with many unique physical and chemical characteristics, and it has become the frontier of international research in recent years. Ionic liquids provide new opportunities for developing clean technology. This paper introduces the synthesis and preparation methods of ionic liquids, and discusses the applications of ionic liquids in CO2 capture, conversion and utilization, electrolytic/ electroplating aluminium, SO2 absorption, wastewater treatment, waste plastics degradation and recycling. Furthermore, the future development trends of ionic liquids are also discussed. Contents 
1 Introduction 
2 Synthesis and preparation of ionic liquids
2.1 Common synthesis methods 
2.2 Outfield intensifying methods 
2.3 Microreactor methods 
3 Application of ionic liquids
3.1 Application in CO2 capture, conversion and utilization 
3.2 Application in electrolytic/ electroplating aluminium
3.3 Application in SO2 absorption 
3.4 Application in wastewater treatment
3.5 Application in degradation and recycling of waste plastics 
4 Conclusions and prospects
Keywords:ionic liquids  preparation  application  green chemistry  clean process  
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