Studies on the synthesis of apoptolidin A. 1. Synthesis of the C(1)-C(11) fragment |
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Authors: | Handa Masaki Scheidt Karl A Bossart Martin Zheng Nan Roush William R |
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Institution: | Department of Chemistry, Scripps-Florida, Jupiter, Florida 33458, USA. |
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Abstract: | A synthesis of the C(1)-C(11) fragment of apoptolidin A has been accomplished by a convergent route involving the stereoselective glycosidation of 9 and the Suzuki cross-coupling reaction of bromodienoate 7 and the vinylborane generated via chemoselective hydroboration of diyne 6 with diisopinocampheylborane. |
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