| 聚N-乙烯咔唑与硝基芴酮类在不同溶剂中形成的电荷转移复合物 |
| |
| 引用本文： | 李桂芳,赵扬,刘昌炎.聚N-乙烯咔唑与硝基芴酮类在不同溶剂中形成的电荷转移复合物[J].物理化学学报,1987,3(5):551-554. |
| |
| 作者姓名： | 李桂芳 赵扬 刘昌炎 |
| |
| 作者单位： | Institute of Chemistry; Academia Sinica; Beijing |
| |
| 摘 要： |
|
| 收稿时间： | 1986-04-09 |
| 修稿时间： | 1986-11-25 |
THE CHARGE-TRANSFER COMPLEXES OF POLY (N-VINYL-CARBAZOLE) AND NITROFLUORENONES IN DIFFERENT SOLVENTS |
| |
| Li Guifang,Zhao Yang,Liu Changyan.THE CHARGE-TRANSFER COMPLEXES OF POLY (N-VINYL-CARBAZOLE) AND NITROFLUORENONES IN DIFFERENT SOLVENTS[J].Acta Physico-Chimica Sinica,1987,3(5):551-554. |
| |
| Authors: | Li Guifang Zhao Yang Liu Changyan |
| |
| Institution: | Institute of Chemistry; Academia Sinica; Beijing |
| |
| Abstract: | The charge-transfer complexes of poly(N-vinylcarbazole) (Mn=7200) and nitro- fluorenones were studied with VPO in different solvents. The relationship between equilibrium constant and solvent dipole moment was examined. The results obtained from polymer and model compound were compared, and the reason of their difference was explained. The relationship between the equilibrium constant and the molecular weight was given: InK_(CT)=InK_(CT)~∞+2M_0/M(InK°-InK~∞) |
| |
| Keywords: | |
|
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
