| 一例夹心型混合价锑钼酸盐的合成、结构及性质 |
| |
| 引用本文： | 杨宗斐,牟秋水,王亚平,马鹏涛,王敬平,牛景杨.一例夹心型混合价锑钼酸盐的合成、结构及性质[J].无机化学学报,2019,35(11):2101-2107. |
| |
| 作者姓名： | 杨宗斐 牟秋水 王亚平 马鹏涛 王敬平 牛景杨 |
| |
| 作者单位： | 河南大学化学化工学院, 开封 475004,河南大学化学化工学院, 开封 475004,河南大学化学化工学院, 开封 475004,河南大学化学化工学院, 开封 475004,河南大学化学化工学院, 开封 475004,河南大学化学化工学院, 开封 475004 |
| |
| 基金项目： | 国家自然科学基金（No.21371048，21671056）和河南省自然科学基金（No.134300510035）资助项目 |
| |
| 摘 要： | 以(NH_4)_6Mo_7O_(24)·4H_2O、Sb_2O_3和Sb_2O_5等为原料,利用常规水溶液法合成了一例结构新颖的含有混合价锑的杂多钼酸盐:(CH3)4N]8Na41H17(SbⅢ3O3)(SbⅤMo6O24)2]6·162H2O (1),并通过元素分析、红外光谱、热重分析和X射线单晶衍射等分析手段对化合物1进行了表征。化合物1含有夹心型的多酸阴离子簇(Sb3O3)(SbMo6O24)2]11-,并进一步通过Na+连接形成二维结构。此外,我们还研究了该化合物的变色性质。当该化合物的粉末被加热或氙灯(300 W)照射时,其颜色由淡黄色变为青黄色或棕褐色。
|
| 关 键 词： | 多金属氧簇 夹心型 晶体结构 变色性质 |
| 收稿时间： | 2019/9/14 0:00:00 |
| 修稿时间： | 2019/10/11 0:00:00 |
Synthesis, Structure and Properties of a Sandwich-Type Polyoxomolybdate Containing Mixed-Valence Antimony |
| |
| YANG Zong-Fei,MU Qiu-Shui,WANG Ya-Ping,MA Peng-Tao,WANG Jing-Ping and NIU Jing-Yang.Synthesis, Structure and Properties of a Sandwich-Type Polyoxomolybdate Containing Mixed-Valence Antimony[J].Chinese Journal of Inorganic Chemistry,2019,35(11):2101-2107. |
| |
| Authors: | YANG Zong-Fei MU Qiu-Shui WANG Ya-Ping MA Peng-Tao WANG Jing-Ping and NIU Jing-Yang |
| |
| Institution: | Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China,Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China,Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China,Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China,Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China and Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China |
| |
| Abstract: | |
| |
| Keywords: | polyoxometalates sandwich type crystal structure allochroic properties |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
